微波輔助聚合物化學

微波輔助聚合物化學：Heck反應， 酯交換反應，Baeyer- Villiger氧化反應，惡唑啉（oxazoline）聚合反應，丙烯酰胺以及多孔材料聚合反應

摘要
    若干問題仍然開放論及微波輻射對有機和高分子化學的不同影響。因此, 對相關(guān)的調(diào)查實驗結(jié)果進行分析，我們闡明三個微波輻射的主要影響：有效的非接觸式加熱，加*果，以及我們專門稱的特殊效果。 
    在本文中，*: 利用HECK-縮聚反應（ HECK-POLYCONDENSATION） 以及通過微波輔助合成聚合物（2, 5-dibutoxy-1, 4-phenylenevinylene）作為一個例子證明微波的 “有效地加熱（EFFICIENT HEATING）”。第二: 通過Baeyer–Villiger 反應合成較高內(nèi)酯的1-oxa-2-oxocyclooctanone and 1-oxa-2-oxocyclononanon作為一個例子證明微波的 “加*果（ACCELERATING EFFECT）” 。第三:我們zui近的調(diào)查工作也給予更詳細的微波效應的解釋，并提供特殊微波效果（SPECIAL MICROWAVE EFFECT）的實例。微波合成。
 

Microwave-assisted polymer chemistry: Heck-reaction,transesterification, Baeyer–Villiger oxidation, oxazoline polymerization, acrylamides, and porous materials

Abstract—Several questions are still open concerning the different effects of microwave （MW） irradiation in organic and macromolecular chemistry. Analyzing experimental results on a relatively broad investigation area, we came to elucidate three main effects of microwave irradiation: efficient non-contact heating, an accelerating effect, and what we term a special effect.
In this paper, we report the first MW assisted synthesis of poly （2, 5-dibutoxy-1, 4-phenylenevinylene） via Heck-polycondensation as an example for efficient heating. The facile synthesis of the higher lactones 1-oxa-2-oxocyclooctanone and 1-oxa-2-oxocyclononanone via Baeyer–Villiger reaction offers indeed an example for theMW-accelerating effect. A survey of our recent work is also given to explain the effects more in detail and to provide examples of the special MWeffect.

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